|
|
germacra-1(10),4,11(13)-trien-12-al + O2 + reduced_[NADPH-hemoprotein_reductase] <=> germacra-1(10),4,11(13)-trien-12-oate + oxidized_[NADPH-hemoprotein_reductase] + H2O + H+
|
not assigned
|
–
|
| |
MetaCyc:
RXN-8970
|
|
|
|
germacra-1(10),4,11(13)-trien-12-ol + reduced_[NADPH-hemoprotein_reductase] + O2 <=> germacra-1(10),4,11(13)-trien-12-al + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-8969
|
|
|
|
germacra-1(10),4,11(13)-trien-12-oate + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 8beta-hydroxygermacra-1(10),4,11(13)-trien-12-oate + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.168
germacrene A acid 8beta-hydroxylase
|
–
|
| |
MetaCyc:
RXN-15460
|
|
|
|
6alpha-hydroxygermacra-1(10),4,11(13)-trien-12-oate + H+ <=> (+)-costunolide + H2O
|
1.14.14.150
costunolide synthase
|
–
|
| |
BRENDA:
BR52442
KEGG:
R12132
MetaCyc:
RXN-15459
|
|
|
|
8beta-hydroxygermacra-1(10),4,11(13)-trien-12-oate + H+ <=> inunolide + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20055
|
|
|
|
germacra-1(10),4,11(13)-trien-12-oate + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 8alpha-hydroxygermacra-1(10),4,11(13)-trien-12-oate + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-20049
|
|
|
|
8alpha-hydroxygermacra-1(10),4,11(13)-trien-12-oate + H+ <=> 8-epi-inunolide + H2O
|
1.14.14.170
8-epi-inunolide synthase
|
–
|
| |
BRENDA:
BR52569
KEGG:
R12274
MetaCyc:
RXN-20050
|
|
|
|
(2E,6E)-farnesyl_diphosphate <=> germacrene_A + diphosphate
|
4.2.3.23
germacrene-A synthase
4.2.3.9
aristolochene synthase
|
–
–
|
| |
BRENDA:
BR50766;
BS378383
KEGG:
R07649
MetaCyc:
RXN-11527
SABIO-RK:
15408
|
|
|
|
germacrene_A + O2 + reduced_[NADPH-hemoprotein_reductase] <=> germacra-1(10),4,11(13)-trien-12-ol + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
not assigned
|
–
|
| |
MetaCyc:
RXN-8962
|
|
|
|
germacra-1(10),4,11(13)-trien-12-oate + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 6alpha-hydroxygermacra-1(10),4,11(13)-trien-12-oate + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-15458
|
|
